STEVENS
PASTE HARDENER Chemical Name DIBENZOYL
PEROXIDE, 50% PASTE WITH DIISOBUTYL PHTHALATE
This product is to be considered as a preparation in
conformance to EC directives.
Company Name Automotive Bodyfillers Ltd
Company Address Unit 8, Zan Industrial Park, Crewe Road,
Sandbach, Cheshire CW11 4PR
Telephone/Fax 01270 766685
2. COMPOSITION/INFORMATION ON INGREDIENTS
Number %
w/w
CAS-number
Chemical name
1
50.0
94-36-0
Dibenzoyl peroxide
2
27.0
84-69-5
Diisobutyl phthalate
Number
EEC-number
Annex-1
number
Symbol(s)
Risk phrase(s)
1
2023276
617-008-00-0
E Xi
R2 R36 R43 R7
2
2015532
none
none
Other information Balance: non-hazardous
ingredients.
3. HAZARDS IDENTIFICATION
May cause fire.
Irritating to eyes.
May cause sensitisation by skin contact.
4. FIRST AID MEASURES
Symptoms and effects
Irritating to eyes. May cause sensitisation by skin contact.
FIRST AID
General In all cases of doubt, or when symptoms persist, seek
medical attention. Inhalation Move to fresh air, rest, half upright position, loosen
clothing. Seek medical advice after significant exposure. Skin Remove contaminated clothing, wash with soap and copious
amounts of water. In case of skin eruption seek medical advice. Eye Rinse thoroughly with plenty of water. Eyelids should be held
away from the eyeball to ensure thorough rinsing. Seek medical advice if
irritation develops. Ingestion
DO NOT
induce vomiting because of risk of aspiration. Seek medical advice. Advice to physician. No additional information available.
5. FIRE-FIGHTING MEASURES
Extinguishing media Water spray, foam, fire-extinguishing powder,
carbon dioxide.
Extinguish a small fire with powder or carbon dioxide then apply water
to prevent re-ignition. Unsuitable Halones extinguishing media
Special exposure If involved in a fire, it will support combustion.
In case of fire and/or hazards explosion do not breathe fumes. Hazardous decomposition/ not determined combustion products
Protective equipment Wear suitable protective clothing. Other information Cool closed containers with water.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions For personal protection see Section 8. Environmental precautions Collect as much as possible in a clean
container for (preferable) reuse or disposal. Do not empty into drains. Methods for cleaning up Sweep up with dustpan and brush off inert
material, flushing the remainder with water. Absorb the remainder with
e.g. vermiculite.
7. HANDLING AND STORAGE
Handling Never weigh out in the storage room. Keep product and
emptied container away from heat and sources of ignition. No sparking
tools should be used. Never bring peroxide into direct contact with
accelerator during processing. Weigh out and add peroxide and
accelerator separately. Fire and explosion Use explosion protected equipment. Keep away
from sources prevention of ignition. No smoking. Storage requirements Keep away from reducing agents (e.g.
amines), acids, alkalis and heavy metal compounds (e.g. accelerators,
driers, metal soaps). Store on accordance with local/national
regulations. Store in a dry, well-ventilated place away from sources of
heat and direct sunlight. Do not mix with peroxide accelerators, Do not
mix with reducing agents. Keep container tightly closed in a cool,
well-ventilated place. Keep container upright to prevent leakage. Other information When using do not eat, drink or smoke. Wash
thoroughly after handling. Keep working clothes separate and do not take
them home.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Smooth, unctuous
paste.
Density 1150-1170 kg/m (20 C) Colour Bulk
density
not determined Odour Faint
Solubility in water Insoluble Boiling point/range Do not distil
(Decomposes) Solubility
in other solvents
Melting point/range -10
C
pH value slightly Acidic character Flash point Above the SADT
value
Partition coefficient not determined n-octanol/water
Flammability not
determined
Relative vapour density not determined
( air = 1 )
Auto ignition temperature > 380
C
Viscosity thixotropic paste Explosive properties no
Active oxygen content 3.24-3.37% Explosion limits not
applicable
Peroxide content 49.0-51.0% Oxidising properties not
applicable
SADT 50 C. See also Section 10:
Other information. Vapour pressure not
determined
Specific conductivity not determined.
10. STABILITY AND REACTIVITY
Stability A dangerous self-accelerating decomposition reaction
and, under certain circumstances, explosion or fire can be caused by
direct contact with incompatible substances or by thermal decomposition
at and above the following temperature: +50 C. Conditions to avoid Violent reactions may be expected with acid,
alkali, heavy metals and reducing agents. Avoid contact with rust. Do
not mix with peroxide accelerators. Do not mix with reducing agents. Materials to avoid Use only Stainless steel 316, PVC,
polyethylene or glass-lined equipment. Hazardous decomposition products not determined
Other information The SADT (self accelerating decomposition
temperature) is an experimentally derived temperature at which the
product in a typical package will undergo self accelerating
decomposition.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Oral rat:> 5000 mg/kg Inhalation rat:> 24.3 mg/l Irritation
Skin Non-irritating (4 hours exposure time) Eyes Mildly irritating ( 5 min exposure time); Moderately
irritating Genotoxicity Ames test: not mutagenic Other toxicological information
12. ECOLOGICAL INFORMATION
Name Based on: Dibenzoyl peroxide 78% Ecotoxicity
fish Acute toxicity, 96h LC50 = 2.0 mg/l. (Poecilia reticulata.) bacteria Activated sludge respiration inhibition test EC50 = 35
mg/l. Fate Degradation Biotic Readily biodegradable (Closed bottle
test)
13. DISPOSAL CONSIDERATIONS
Product Probably in controlled incineration but according to
local regulations.
Sweep up with dustpan and brush off inert material, flushing the
remainder with water. Absorb the remainder with e.g. vermiculite. Contaminated packaging Collect for recycling or most probably
controlled incineration. Other information Dilute before burning with organic solvents.
Controlled incineration according to local regulations is always
preferred. If not possible burn in small portions on a remote place,
using a torch with a long rod to ignite the material.
14. TRANSPORT INFORMATION
Land Transport
ADR class 5.2 ADR item number 8b RID class 5.2 RID item number 8b Hazard Identification No.Substance Identification No.
Sea Transport
IMO/IMDG code page 5228
Class 5.2 Packing Group II
UN number 3108 EMS 5.2 -
01
MFAG 735 Marine pollutant no
Proper shipping name Organic peroxide type e,
solid; (Dibenzoyl peroxide)
Other information 15. REGULATORY INFORMATION Product label name Dibenzoyl peroxide,50% paste with diisobutyl
phthalate Labelling according to EC directives
Annex-1 number not applicable Classification based on
Symbol(s) OXIDISING
IRRITANT
Risk) phrases(s) R7. May cause fire.
R36. Irritating to eyes.
R43. May cause some sensitisation by
skin contact.
16. OTHER INFORMATION
The information included in this Safety Data Sheet is accurate
to the best of our knowledge at the time of compilation.
Further advice pertaining to the use of this material may be obtained
from our technical department.